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MCQ on Class 11 Chemistry Chapter 12 Organic Chemistry Some Basic Principles And Techniques

(1) Which of the following behaves both as a nucleophile and as an electrophile?
[A] CH3C ≡ N
[B] CH3OH
[C] CH2 = CHCH3
[D] CH3NH2
Answer: CH3C ≡ N
(2) A crystalline solid possess which one of the following property?
[A] Irregularity
[B] Non- symmetric
[C] Perfect geometric pattern
[D] non- stability
Answer: Perfect geometric pattern

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(3) Inductive effect involves
[A] displacement of σ electrons
[B] delocalization of π electrons
[C] delocalization of σ-electrons
[D] displacement of π-electrons
Answer: displacement of σ electrons
(4) Which element is estimated by Carius method
[A] Carbon
[B] Hydrogen
[C] Halogen
[D] Nitrogen
Answer: Halogen
(5) If there is no rotation of plane polarized light by a compound in a specific solvent, thought to be chiral, it may mean that
[A] The compound may be a racemic mixture
[B] The compound is certainly a chiral
[C] The compound is certainly meso
[D] There is no compound in the solvent.
Answer: The compound is certainly meso
(6) If 0.228 g of silver salt of dibasic acid gave a residue of 0.162 g of silver on ignition then molecular weight of the acid is
[A] 70
[B] 80
[C] 90
[D] 100
Answer: 90
(7) Which one of the following conformations of cyclohexane is chiral?
[A] Twist boat
[B] Rigid
[C] Chair
[D] Boat
Answer: Twist boat
(8) The compound is known by which of the following names
[A] Bicyclo-[2, 2, 2] octane
[B] Bicyclo-[2, 2, 1] octane
[C] Bicyclo-[1, 2, 1] octane
[D] Bicyclo-[1, 1, 1] octane
Answer: Bicyclo-[2, 2, 2] octane
(9) 0.0833mol of carbohydrate of empirical formula CH2O contain 1 g of hydrogen. The molecular formula of the carbohydrate is
[A] C5H10O5
[B] C3H4O3
[C] C12H22O11
[D] C6H12O6
Answer: C6H12O6
(10) In the Dumas method, the nitrogen present in organic compound gets converted to
[A] Sodium Cyanide
[B] Gaseoue Ammonia
[C] Dinitrogen Gas
[D] Ammonium Sulphate.
Answer: Dinitrogen Gas
(11) 59 g of an amide obtained from a carboxylic acid, RCOOH, liberated 17 g of ammonia upon heating with alkali. The acid is
[A] Formic Acid
[B] Acetic Acid
[C] Propionic Acid
[D] Benzoic Acid
Answer: Acetic Acid
(12) What is the correct IUPAC name of

[A] 4-methoxy-2-nitrobenzaldehyde
[B] 4-formyl-3-nitro anisole
[C] 4-methoxy-6-nitrobenzaldehyde
[D] 2-formyl-5-methoxy nitrobenzene
Answer: 4-methoxy-2-nitrobenzaldehyde
(13) Insulin contains 3.4% sulphur. The minimum molecular weight of insulin is
[A] 350
[B] 470
[C] 560
[D] 940
Answer: 940
(14) Which one is strongest acid among following options?
[A] CH2FCOOH
[B] CH2ClCOOH
[C] CHCl2COOH
[D] CHF2COOH
Answer: CH2ClCOOH
(15) An organic compound which produces a bluish green coloured flame on heating in presence of copper is
[A] Chlorobenzene
[B] Benzaldehyde
[C] Aniline
[D] Benzoic acid
Answer: Benzoic acid
(16) Which of the following cannot be represented by resonance structures?
[A] Dimethyl ether
[B] Nitrate anion
[C] Carboxylate anion
[D] Toluene
Answer: Dimethyl ether
(17) The displacement of electrons in a multiple bond in the presence of attacking reagent is called
[A] Inductive effect
[B] Electromeric effect
[C] Resonance
[D] Hyper conjugation.
Answer: Electromeric effect
(18) 0.0833mol of carbohydrate of empirical formula CH2O contain 1g of hydrogen. The molecular formula of the carbohydrate is
[A] C5H10O5
[B] C3H4O3
[C] C12H22O11
[D] C6H12O6
Answer: C6H12O6
(19) Identify the chiral molecule among the following:
[A] Isopropyl alcohol
[B] 2-pentanol
[C] 1-bromo 3-butene
[D] Isobutyl alcohol
Answer: Isobutyl alcohol
(20) If two compounds have the same empirical formula but different molecular formula they must have
[A] Different percentage composition
[B] Different molecular weight
[C] Same viscosity
[D] Same vapour density
Answer: Different molecular weight

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