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Class 11 Chemistry Chapter 4 Chemical Bonding and Molecular Structure MCQ Questions With Answers

(1) Which of the following is a linear molecule?
[A] ClO2
[B] CO2
[C] NO2
[D] SO2
Answer: CO2
(2) The outer orbitals of C in ethene molecule can be considered to be hybridized to give three equivalent sp² orbitals. The total number of sigma (s) and pi (p) bonds in ethene molecule is
[A] 1 sigma (s) and 2 pi (p) bonds
[B] 3 sigma (s) and 2 pi (p) bonds
[C] 4 sigma (s) and 1 pi (p) bonds
[D] 5 sigma (s) and 1 pi (p) bonds
Answer: 5 sigma (s) and 1 pi (p) bonds

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(3) The structure of IF7 is
[A] Pentagonal bipyramid
[B] Square pyramid
[C] Trigonal bipyramid
[D] Octahedral
Answer: Pentagonal bipyramid
(4) The species having pyramidal shape is
[A] SO3
[B] BrF3
[C] SiO32-
[D] OSF2
Answer: OSF2
(5) The charge/size ratio of a cation determines its polarizing power. Which one of the following sequences represents the increasing order of the polarizing order of the polarizing power of the cationic species, K+, Ca++, Mg2+, Be2+?
[A] Ca2+ < Mg2+ < Be+ < K+
[B] Mg2+ < Be2+ < K+ < Ca2+
[C] Be2+ < K+ < Ca2+ < Mg2+
[D] K+ < Ca2+ < Mg2+ < Be2+
Answer: K+ < Ca2+ < Mg2+ < Be2+
(6) Among the following mixtures, dipole-dipole as the major interaction, is present in
[A] benzene and ethanol
[B] acetonitrile and acetone
[C] KCl and water
[D] benzene and carbon tetrachloride
Answer: acetonitrile and acetone
(7) Dipole-induced dipole interactions are present in which of the following pairs?
[A] H2O and alcohol
[B] Cl2 and CCl4
[C] HCl and He atoms
[D] SiF4 and He atoms
Answer: HCl and He atoms
(8) Based on lattice enthalpy and other considerations which one the following alkali metals chlorides is expected to have the higher melting point?
[A] RbCl
[B] KCl
[C] NaCl
[D] LiCl
Answer: NaCl
(9) The number of types of bonds between two carbon atoms in calcium carbide is
[A] Two sigma, two pi
[B] One sigma, two pi
[C] One sigma, one pi
[D] Two sigma, one pi
Answer: One sigma, two pi
(10) The maximum number of hydrogen bonds that a molecule of water can have is
[A] 1
[B] 2
[C] 3
[D] 4
Answer: 4
(11) An atom of an element A has three electrons in its outermost orbit and that of B has six electrons in its outermost orbit. The formula of the compound between these two will be
[A] A3B6
[B] A2B3
[C] A3B2
[D] A2B
Answer: A2B3
(12) Which of the following types of hybridisation leads to three dimensional geometry of bonds around the carbon atom?
[A] sp
[B] sp²
[C] sp³
[D] None of these
Answer: sp²
(13) The value of n in the molecular formula BenAl2Si6O18 is
[A] 3
[B] 5
[C] 7
[D] 9
Answer: 3
(14) Among the following mixtures, dipole-dipole as the major interaction, is present in
[A] benzene and ethanol
[B] acetonitrile and acetone
[C] KCl and water
[D] benzene and carbon tetrachloride
Answer: acetonitrile and acetone
(15) Among the following the maximum covalent character is shown by the compound
[A] MgCl2
[B] FeCl2
[C] SnCl2
[D] AlCl3
Answer: AlCl3
(16) Which of the following will have the lowest boiling point?
[A] 2-MethylButane
[B] 2-MethylPropane
[C] 2,2-Dimethylpropane
[D] n-Pentane
Answer: n-Pentane
(17) Which one of the following does not have sp² hybridised carbon?
[A] Acetone
[B] Acetic acid
[C] Acetonitrile
[D] Acetamide
Answer: Acetonitrile
(18) The hybrid state of sulphur in SO2 molecule is :
[A] sp²
[B] sp³
[C] sp
[D] sp³d
Answer: sp²
(19) The number of nodal planes present in s × s antibonding orbitals is
[A] 1
[B] 2
[C] 0
[D] 3
Answer: 1
(20) The bond length between hybridised carbon atom and other carbon atom is minimum in
[A] Propane
[B] Butane
[C] Propene
[D] Propyne
Answer: Propyne

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