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Multiple Choice Questions and Answers for Class 11 Chemistry Chapter 4 Chemical Bonding and Molecular Structure

(1) Which of the following statements are not correct?
[A] NaCl being an ionic compound is a good conductor of electricity in the solid-state.
[B] In canonical structures, there is a difference in the arrangement of atoms.
[C] Hybrid orbitals form stronger bonds than pure orbitals.
[D] VSEPR Theory can explain the square planar geometry of XeF4.
Answer: A, B
(2) Species having same bond order are :
[A] N2
[B] N2-
[C] F2+
[D] O2
Answer: C. D

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(3) Diamagnetic species are those which contain no unpaired electrons. Which among the following are diamagnetic?
[A] N2
[B] N22-
[C] O2
[D] O22-
Answer: A, D
(4) Which of the following statements are correct about CO32-?
[A] The hybridisation of the central atom is sp3.
[B] Its resonance structure has one C–O single bond and two C=O double bonds.
[C] The average formal charge on each oxygen atom is 0.67 units.
[D] All C–O bond lengths are equal.
Answer: C, D
(5) Which of the following species have the same shape?
[A] CO2
[B] CCl4
[C] O3
[D] NO2
Answer: C, D
(6) CO is isoelectronic with
[A] NO+
[B] N2
[C] SnCl2
[D] NO2
Answer: A, B
(7) Which of the following attain the linear structure:
[A] BeCl2
[B] NCO+
[C] NO2
[D] CS2
Answer: A, D
(8) Which of the following have identical bond order?
[A] CN–
[B] NO+
[C] O2–
[D] O2
Answer: A, B
(9) Amongst the following elements whose electronic configurations are given below, the one having the highest ionisation enthalpy is
[A] [Ne]3s2 3p1
[B] [Ne]3s2 3p3
[C] [Ne]3s2 3p2
[D] [Ar]3d10 4s2 4p3
Answer: [Ne]3s2 3p3
(10) The electronic configuration of the outer most shell of the most electronegative element is
[A] 2s2 2p5
[B] 3s2 3p5
[C] 4s2 4p5
[D] 5s2 5p
Answer: 2s2 2p5
(11) Which of the following options represents the correct bond order :
[A] O2–> O2 > O2+
[B] O2–< O2 < O2+
[C] O2–> O2 < O2+
[D] O2–< O2 > O2
Answer: O2–< O2 < O2+
(12) Which of the following statement is not correct from the viewpoint of molecular orbital theory?
[A] Be2 is not a stable molecule.
[B] He2 is not stable but He2+ is expected to exist.
[C] Bond strength of N2 is maximum amongst the homonuclear diatomic molecules belonging to the second period.
[D] The order of energies of molecular orbitals in N2 molecule is σ2s < σ*2s < σ2pz< (π2px = π2py ) < (π*2px= π*2py) < σ*2pz
Answer: The order of energies of molecular orbitals in N2 molecule is σ2s < σ*2s < σ2pz< (π2px = π2py ) < (π*2px= π*2py) < σ*2pz
(13) Which of the following order of energies of molecular orbitals of N2 is correct?
[A] (π2py ) < (σ2pz) < (π*2px) ≈ (π*2py)
[B] (π2py ) > (σ2pz) > (π*2px) ≈ (π*2py )
[C] (π2py ) < (σ2pz) > (π*2px) ≈ (π*2py )
[D] (π2py ) > (σ2pz) < (π*2px) ≈ (π*2py )
Answer: (π2py ) < (σ2pz) < (π*2px) ≈ (π*2py)
(14) The bond between B and C will be
[A] Ionic
[B] Covalent
[C] Hydrogen
[D] Coordinate
Answer: Covalent
(15) The molecular formula of the compound formed from B and C will be
[A] BC
[B] B2C
[C] BC2
[D] BC3
Answer: BC3
(16) The stable form of C may be represented by the formula :
[A] C
[B] C2
[C] C3
[D] C4
Answer: C2
(17) The stable form of A may be represented by the formula :
[A] A
[B] A2
[C] A3
[D] A4
Answer: A
(18) Which of the following angle corresponds to sp2 hybridisation?
[A] 90°
[B] 120°
[C] 180°
[D] 109°
Answer: 120°
(19) If the electronic configuration of an element is 1s2 2s2 2p6 3s2 3p6 3d2 4s2, the four electrons involved in chemical bond formation will be_____.
[A] 3p6
[B] 3p6, 4s2
[C] 3p6, 3d2
[D] 3d2, 4s2
Answer: 3d2, 4s2
(20) In which of the following substances will hydrogen bond be strongest?
[A] HCl
[B] H2O
[C] HI
[D] H2S
Answer: H2O

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