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CBSE Class 12 Chemistry Quiz | CBSE Class 12 Chemistry Objective Type Questions & Answers

(21) An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because _________ .
[A] it gains water due to osmosis.
[B] it loses water due to reverse osmosis.
[C] it gains water due to reverse osmosis.
[D] it loses water due to osmosis.
Answer: it loses water due to reverse osmosis.
(22) In comparison to a 0.01 M solution of glucose, the depression in freezing point of a 0.01 M MgCl2 solution is _________ .
[A] the same
[B] about twice
[C] about three times
[D] about six times
Answer: about three times

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(23) Which of the following aqueous solutions should have the highest boiling point?
[A] 1.0 M NaOH
[B] 1.0 M Na2SO4
[C] 1.0 M NH4NO3
[D] 1.0 M KNO3
Answer: 1.0 M Na2SO4
(24) Considering the formation, breaking and strength of hydrogen bond, predict which of the following mixtures will show a positive deviation from Raoult’s law?
[A] Methanol and acetone.
[B] Phenol and aniline.
[C] Chloroform and acetone.
[D] Nitric acid and water.
Answer: Methanol and acetone.
(25) Low concentration of oxygen in the blood and tissues of people living at high altitude is due to _________ .
[A] low temperature
[B] low atmospheric pressure
[C] high atmospheric pressure
[D] both low temperature and high atmospheric pressure
Answer: low atmospheric pressure
(26) The number of moles of NaCl in 3 litres of 3M solution is
[A] 9
[B] 27
[C] 1
[D] 3
Answer: 9
(27) The molality of pure water is
[A] 60.5
[B] 55.5
[C] 50.5
[D] 18
Answer: 55.5
(28) If E°Fe2+/Fe = -0.441 V and E°Fe2+/Fe2+ = 0.771 V, the standard EMF of the reaction, Fe + 2Fe3+ → 3Fe2+ will be
[A] 1.212 V
[B] 1.653 V
[C] 0.111 V
[D] 0.330 V
Answer: 1.212 V
(29) The reaction, 3ClO– (aq) → ClO3 (aq) + 2Cl– (aq) is an example of
[A] Oxidation reaction
[B] Reduction reaction
[C] Disproportionation reaction
[D] Decomposition reaction
Answer: Disproportionation reaction
(30) NH4NC>3 is used in salt bridge because
[A] it forms a jelly like material with agar-agar.
[B] it is a weak electrolyte.
[C] it is a good conductor of electricity.
[D] the transport number of NH4+ and NO3– ions are almost equal.
Answer: the transport number of NH4+ and NO3– ions are almost equal.
31 limiting molar conductivity of Ca2+ and Cl– are 119.0 and 76.3 S cm2 mol-1, then the value of limiting molar conductivity of CaCl2 will be
[A] 195.3 S cm2 mol-1
[B] 271.6 S cm2 mol-1
[C] 43.3 S cm2 mol-1
[D] 314.3 S cm2 mol-1.
Answer: 271.6 S cm2 mol-1
32 The charge required for the reduction of 1 mol of MnO2– to MnO2 is
[A] 1 F
[B] 3 F
[C] 6 F
[D] 5 F
Answer: 3 F
33 Λ of M/32 solution of weak acid is 8 S cm2 mol-1 and limiting molar conductivity is 400 S cm2 mol1. Ka for acid is
[A] 1.25 × 10-6
[B] 6.25× 10-4
[C] 1.25 × 10-4
[D] 1.25 × 10-5
Answer: 1.25 × 10-5
34 While charging the lead storage battery _________ .
[A] PbSO4 anode is reduced to Pb.
[B] PbSO4 cathode is reduced to Pb.
[C] PbSO4 cathode is oxidised to Pb.
[D] PbSO4 anode is oxidised to PbO2.
Answer: PbSO4 anode is reduced to Pb.
35 A conductivity cell containing electrodes made up of
[A] Gold
[B] Silver
[C] Platinised platinum
[D] Copper
Answer: Platinised platinum
36 Ag+(aq) + e– → Ag(s) E° = + 0.80 V Fe2+(aq)+ + 2e– → Fe(s) E° = – 0.44 V What is emf of Fe(s) + 2Ag+(aq) → Fe2+(aq) + 2Ag(s)
[A] 1.16 V
[B] 1.24 V
[C] 2.04 V
[D] -1.16 V
Answer: 1.24 V
37 A new galvanic cell of E^u more than E°dl of Daniel cell is connected to Daniel cell in a manner that new cell gives electrons to cathode, what will happen
[A] Ecell will increase
[B] Ecell will decrease
[C] No change will take place
[D] Daniel cell will work as electrolytic cell where Zn will be deposite on zinc rod and copper will dissolve from copper rod.
Answer: Ecell will decrease
38 The emf of the cell: Ni / Ni2+ (1.0 M) // Au3+ (1.0 M) / Au (E° = -0.25 V for Ni2+/Ni; E° = 1.5 V for Au3+/Au) is
[A] 1.25 V
[B] -1.25 V
[C] 1.75 V
[D] 2.0 V
Answer: 1.75 V
39 The half life period of first order reaction is 1386 seconds. The specific rate constant of the reaction is
[A] 0.5 × 10-3 s-1
[B] 5.0 × 10-3 s-1
[C] 0.5 × 10-2 s-1
[D] 5.0 × 10-2 s-1
Answer: 0.5 × 10-3 s-1
40 The rate constant of a reaction A → B is 0.6 × 103 mole per second. If the concentration of [A] is 5 M, then what will be concentration of [B] after 20 months?
[A] 3.60 M
[B] 0.36 M
[C] 0.72 M
[D] None of these
Answer: 0.72 M

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