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Chemical Bonding Quiz | Chemical Bonding Objective Type Questions & Answers

(21) Among the following isostructural compounds, which one has highest lattice energy ?
[A] LiCl
[B] MgO
[C] NaCl
[D] LiF
Answer: MgO
(22) A bonded molecule MX3 is T-shaped. The number of non-bonding pairs of electrons is :
[A] 0
[B] 2
[C] 1
[D] Can be predicted only if atomic number of M is known
Answer: 2
(23) In a chemical change from PCl3 −−−→PCl5 the hybrid state of P changes from:
[A] sp2 to sp3
[B] sp3 to sp2
[C] sp3 to sp3d
[D] sp3 to dsp
Answer: sp3 to sp3d
(24) The geometrical arrangement and shape of I−3 are respectively
[A] Trigonal bipyramidal geometry, linear shape
[B] Hexagonal structure, linear shape
[C] Triangular planar geometry, triangular shape
[D] Tetrahedral geometry, pyramidal shape
Answer: Trigonal bipyramidal geometry, linear shape
(25) Which molecules/ions are most paramagnetic?
[A] B2
[B] C2
[C] O+2
[D] O−2
Answer: B2
(26) Which has linear shape but not sp hibridisation ?
[A] XeF2
[B] I−3
[C] CO2
[D] Both 1 and 2
Answer: Both 1 and 2
(27) Which of the following structure is most expected for the molecule XeOF4 ?
[A] Tetrahedral
[B] Square pyramid
[C] Square planar
[D] Octahedral
Answer: Square pyramid
(28) Which is mismatched regarding the shape ?
[A] XeF4 = Square planar
[B] XeOF4 = Square Pyramidal
[C] XeF6 = Distorted Octahedral
[D] XeO3 = Bent Shape
Answer: XeO3 = Bent Shape
(29) The isostere pair is
[A] CO2 and N2O
[B] CO and N2
[C] O2 and NO2
[D] Both (1) and (2)
Answer: Both (1) and (2)
(30) Select the correct order of solubility (in water) from the following:
[A] SrSO4 < CaSO4 < MgSO4 < BeSO4
[B] NaF < KF < RbF < CsF
[C] Ba(OH)2 > SR(OH)2 > Ca(OH)2 > Mg(OH)2
[D] All of these
Answer: All of these
31 Which of the following has largest bond angle.
[A] H2O
[B] F2O
[C] Cl2O
[D] H2S
Answer: Cl2O
32 Amongst H2O, H2S, H2Se and H2Te the one with highest boiling point is:
[A] H2O because of H-bonding
[B] H2Te because of higher molecular weight
[C] H2S because of H-bonding
[D] H2Se because of lower molecular weight
Answer: H2O because of H-bonding
33 Which of the following are isoelectronic and isostructural? NO−3, CO-23, ClO−3, SO3
[A] NO−3, CO-23
[B] SO3, NO−3
[C] ClO−3, CO-23
[D] CO-23, ClO−3
Answer: NO−3, CO-23
34 Which of the following exhibits H-bonding?
[A] CH4
[B] H2Se
[C] N2H2
[D] H2S
Answer: N2H2
35 Which has highest bond angle ?
[A] NH3
[B] H2O
[C] H2S
[D] PH3
Answer: NH3
36 Which has highest bond energy ?
[A] CO
[B] CO+
[C] N2
[D] N+2
Answer: CO+
37 which is the incorrect about bond angles ?
[A] NH3 > NF3
[B] NF3 > PF3
[C] NH3 > PH3
[D] NH3 > H2O
Answer: NF3 > PF3
38 The types of hybrid orbitals of nitrogen in NO2+, NO3- and NH4+ respectively are expected to be
[A] sp, sp3 and sp2
[B] sp, sp2 and sp3
[C] sp2, sp and sp3
[D] sp2, sp3 and sp
Answer: sp, sp2 and sp3
39 Among LiCl, BeCl2, BCl3 and CCl4, the covalent bond character varies as
[A] LiCl < BeCl2 > BCl3 > CCl4
[B] LiCl > BeCl2 < BCl3 < CCl4
[C] LiCl < BeCl2 < BCl3 < CCl4
[D] LiCl > BeCl2 > BCl3 > CCl4
Answer: LiCl < BeCl2 < BCl3 < CCl4
40 Which of the following statement is not correct from the view point of molecular orbital theory ?
[A] Be2 is not a stable molecule
[B] He2 is not a stable but He2+ is expected to exist
[C] Bond strength of N2 is maximum amongst the homonuclear diatomic molecules belonging to the second period
[D] The order of energies of molecular orbitals in N2 molecule is 2s < *2s < 2pz < (2px=2py) < (*2px=*2py) < *2pz
Answer: The order of energies of molecular orbitals in N2 molecule is 2s < *2s < 2pz < (2px=2py) < (*2px=*2py) < *2pz

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