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Organic Chemistry Questions and Answers – Benzene Diazonium Chloride – 2 | Organic Chemistry Multiple Choice Questions and Answers

(1) Replacement of diazo group by other groups is helpful in preparing those substituted aromatic compounds which cannot be prepared which type of reaction?
[A] Direct elimination
[B] Addition reaction
[C] Direct substitution
[D] Replacement reaction
Answer: Direct substitution
(2) What happens when benzene diazonium chloride is treated with potassium cyanide in presence of Cu powder?
[A] Benzophenone
[B] Methyl isocyanide
[C] Acetonitrile
[D] Benzonitrile
Answer: Benzonitrile

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(3) By treating diazonium salts with cuprous cyanide or KCN and copper powder it forms which of the following compound?
[A] Citric acid
[B] Benzoic acid
[C] Aryl nitrile
[D] Oxalic acid
Answer: Aryl nitrile
(4) Benzene diazonium chloride forms orange red dye with which of the following compound?
[A] Nitrophenol
[B] Benzophenol
[C] Resorcinol
[D] Methanol
Answer: Resorcinol
(5) Which of the following is compound A for following sequence of reaction gave benzoic acid benzoic acid?

[A] Nitrobenzene
[B] Aniline
[C] Benzaldehyde
[D] Amides
Answer: Aniline
(6) In the series of reaction, what are X and Y are respectively?

[A] C6H5−N=N−C6H5, C6H5N+2Cl
[B] C6H5N+2Cl, C6H5−N=N−C6H5
[C] C6H5N+2Cl, C6H5NO2
[D] C6H5NO2, C6H6
Answer: C6H5N+2Cl, C6H5NO2
(7) Aniline in a set of reactions yielded a product D. The structure of product D would be

[A] C6H5CH2NH2
[B] C6H5NHCH2CH3
[C] C6H5NHOH
[D] C6H5CH2OH
Answer: C6H5CH2OH
(8) Azo dye is prepared by the coupling of phenol and which of the following compound?
[A] Diazonium chloride
[B] o-nitro aniline
[C] Benzoic acid
[D] Chlorobenzene
Answer: Diazonium chloride
(9) Identify the product in following order when 3,4,5-Tribromoaniline undergoes diazotisation followed by attack of H3PO2?
[A] 3, 4,5-Tribromobenzene
[B] 1, 2, 3-Tribromobenzene
[C] 2, 4, 6-Tribromobenzene
[D] 3, 4, 5-Tribromo nitro benzene
Answer: 3, 4,5-Tribromobenzene
(10) When diazonium salt solution is treated with KI, it forms which of the following compound?
[A] Bromobenzene
[B] Iodobenzene
[C] Phenol
[D] Acid
Answer: Iodobenzene

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