The reaction of equimolar quantities of Fe(CO)5 and OH– gives a complex species X which on further reaction with MnO2

Q. The reaction of equimolar quantities of Fe(CO)5 and OH gives a complex species X which on further reaction with MnO2 gives species Y. X and Y, respectively, are

(A) [Fe(CO)5(OH)] and Fe2(CO)9

(B) [Fe(CO)4]2– and Mn2(CO)10

(C) [HFe(CO)4] and Fe2O3

(D) [HFe(CO)4] and Fe3(CO)12

Ans: [HFe(CO)4]- and Fe3(CO)12

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