1. The oxidation number of sulphur in Caro’s acid is
- +4
- +5
- +6
- +8
Answer: +6
2. An electrochemical cell generally consists of a cathode and an anode. Which of the following statements is correct with respect to the cathode?
- Oxidation occurs at the cathode
- Electrons move into the cathode
- Usually denoted by a negative sign
- Is usually made up of insulating material
Answer: Electrons move into the cathode
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3. Which of the following is not a characteristic feature of a salt bridge?
- Salt bridge joins the two halves of an electrochemical cell
- It completes the inner circuit
- It is filled with a salt solution (or gel)
- It does not maintain electrical neutrality of the electrolytic solutions of the half-cells
Answer: It does not maintain electrical neutrality of the electrolytic solutions of the half-cells
4. What is the observation when the opposing external applied potential to an electrochemical cell is greater than the cell’s potential?
- The electrochemical cell behaves like an electrolytic cell
- The electrochemical cell stops functioning
- Only oxidation reactions occur in the cell
- Only reduction reactions occur in the cell
Answer: The electrochemical cell behaves like an electrolytic cell
5. The electrochemical cell stops working after sometime. Why ?
- Increase in temperature
- The difference of cell potentials of both electrodes become zero.
- By reversing the direction of reaction taking place in the cell.
- Due to change in concentration
Answer: The difference of cell potentials of both electrodes become zero.
6. The solution of silver nitrate become coloured when pieces of nickle are added to solution of silver nitrate because
- Nickel is oxidised
- Silver is oxidised
- Nickel is reduced
- Silver is precipitated
Answer: Nickel is oxidised
7. Which is the device used for measurement of electrical resistance ?
- Voltmeter
- Wheatstone bridge
- Galvanometer
- Ammeter
Answer: Wheatstone bridge
8. The reaction of electrochemical cell will stop after sometime because _____
- potential of both electrodes becomes zero.
- potential of both electrodes becomes equal.
- one of the electrode is completely corroded.
- reaction will occur in opposite direction.
Answer: one of the electrode is completely corroded.
9. The electricity conducted by 1 mole electron is called _____
- 1 Joule
- 1 volt
- 1 Faraday
- 1 coulomb
Answer: 1 Faraday
10. Electrolytes conduct electric current
- by the movement of ions
- by the movement of atoms
- by the movement of molecules
- by the movement of electrons from the cathode to anode
Answer: by the movement of electrons from the cathode to anode
11. The conductance in electrolyte conductors is due to
- Either movement of electrons or ions
- The flow of free mobile electrons
- Movement of ions
- None of the above
Answer: Movement of ions
12. When equilibrium is reached inside the two half-cells of the electrochemical cells, what is the net voltage across the electrodes?
- 100 lit
- < 1
- = 0
- Not defined
Answer: = 0
13. Which of the following statements is correct regarding Electrochemical cells?
- Cell potential is an extensive property
- Cell potential is an intensive property
- The Gibbs free energy of an electrochemical cell is an intensive property
- Gibbs free energy is undefined for an electrochemical cell
Answer: Cell potential is an intensive property
14. Which of the following is not a type of electrochemical cell?
- Voltaic cell
- Photovoltaic cell
- Electrolytic cell
- Fuel Cell
Answer: Photovoltaic cell
15. Which of the following statements regarding primary cells is false?
- Primary cells cannot be recharged
- They have low internal resistance
- They have an irreversible chemical reaction
- Their initial cost is cheap
Answer: They have low internal resistance
16. Which cell differs from principle point of view?
- Storage cell
- Electrolytic cell
- Fuel cell
- Leclanche cell
Answer: Electrolytic cell
17. The values of standard reduction potential of X, Y and Z metals are 0.34 V, 0.80 V and -0.45 V. Mention their order of strength as reducing agent
- Z > Y > X
- Z > X > Y
- X > Y > Z
- Y > Z > X
Answer: Z > X > Y
18. Which of the following cell is different ?
- Daniel cell
- Voltaic cell
- Galvanic cell
- Electrolytic cell
Answer: Electrolytic cell
19. Which of the following is the most powerful reducing agent?
- H2S
- H2SO3
- SnCl2
- HNO2
Answer: H2S
20. The cell constant of a conductivity cell
- Changes with a change of concentration of electrolyte
- Remains constant for a cell
- changes with a change of electrolyte
- changes with change in temperature
Answer: Remains constant for a cell
21. Why are the saturated solutions of electrolytes for the salt bridge prepared in agar-agar jelly or gelatin?
- The jelly acts as an electrolyte
- It helps the electrolytes to mix with the contents of the half cells
- It helps maintain the electrical polarity between the two half-cell solutions
- It keeps the electrolyte in semi-solid phase and prevents it from mixing with the two half-cell solutions
Answer: It keeps the electrolyte in semi-solid phase and prevents it from mixing with the two half-cell solutions
22. Which of the following is a not a secondary cell?
- Nickel-cadmium cell
- Lead storage cell
- Mercury cell
- Leclanche cell
Answer: Leclanche cell
23. Which reaction take place in electrochemical cell ?
- Oxidation
- Reduction
- Redox
- All the given
Answer: All the given
24. The resistance of any uniform conductor is
- in inverse proportion to its length
- in direct proportion to its length
- in the inverse proportion of the square of its area of cross section
- in direct proportion of the area of its cross section
Answer: in direct proportion to its length
25. What will be the mole ratio of Cu, Ag and Al respectively, when 1 mole electrons passed through CuSO4, AgNO3 and AlCl3 solution ?
- 1 : 1 : 1
- 1 : 2 : 3
- 2 : 1 : 3
- 3 : 6 : 2
Answer: 3 : 6 : 2
26. What is the direction of flow of electrons in an electrolytic cell?
- Anode to cathode externally
- Anode to cathode internally
- Cathode to anode externally
- Cathode to anode in the solution
Answer: Anode to cathode externally
27. What is used for the measurement of accurate potential of electrochemical cell ?
- Galvanometer
- Ammeter
- Voltmeter
- Potentiometer
Answer: Potentiometer
28. Which is more corroded when the iron plates of steamers are connected with block of Zn metal and kept in contact of sea water ?
- Iron
- Zinc
- Both
- Neither of the metals
Answer: Zinc
29. For the cell reaction takes place in electrochemical cell-
- ΔG = 0
- ΔG < 0
- ΔG > 0
- ΔG ≥ 1
Answer: ΔG < 0
30. Which of the following substances can act as both oxidising and reducing agent?
- KMnO4
- K2Cr2O7
- HNO3
- H2O2
Answer: H2O2
31. The reductant may be defined as a substance, whose oxidation no of the atom
- increases
- decreases
- remains constant
- may increases or decreases
Answer: increases
32. Which of the following is not a generally used electrolyte in the salt bridges used to connect the two half-cells of an electrochemical cell?
- NaCl
- KNO3
- KCl
- ZnSO4
Answer: ZnSO4
33. Oxygen has a +2 oxidation state in
- H2O
- H2O2
- F2O
- SO2
Answer: F2O
34. When the salt bridge is removed from a cell, its voltage
- will increase
- will decrease to half
- Fwill decrease to zero2O
- will not change
Answer: will decrease to zero
35. 1 Faraday _____ Coulomb.
- 96000
- 96487
- 96847
- 96748
Answer: 96487
36. Which of the following is not an example of an oxidizing agent?
- hydrogen peroxide
- potassium dichromate
- nitric acid
- hydrogen sulphide
Answer: hydrogen sulphide
37. At which temperatures ceramic materials are known as superconductor ?
- 0 K
- 200 K
- 150 K
- 15 K
Answer: 150 K
38. When a dilute solution of H2SO4 is electrolysed using a platinum electrode, at anode the gas evolved is
- SO3
- SO2
- H2
- O2
Answer: O2