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Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes MCQs | Class 12 Chemistry Chapter 10 Haloalkanes and Haloarenes Objective Type Questions and Answers

(1) Chloropicrin is formed by the reaction of
[A] steam on carbon tetrachloride
[B] nitric acid on chlorobenzene
[C] chlorine on picric acid
[D] nitric acid on chloroform
Answer: nitric acid on chloroform
(2) Fitting reaction can be used to prepare
[A] Toluene
[B] Acetophenon
[C] Diphenyl
[D] Chlorobenzene
Answer: Diphenyl
(3) In the above reaction, the product D is
[A] Propane
[B] 2, 3-Dimethylbutane
[C] Hexane
[D] Allyl bromide
Answer: 2, 3-Dimethylbutane
(4) Fitting reaction can be used to prepare
[A] Toluene
[B] Acetophenon
[C] Diphenyl
[D] Chlorobenzene
Answer: Diphenyl
(5) Identify the end product (C) in the following sequence:
[A]
[B]
[C]
[D]
Answer:
(6)
In the above reaction, the product D is
[A] Propane
[B] 2, 3-Dimethylbutane
[C] Hexane
[D] Allyl bromide
Answer: 2, 3-Dimethylbutane
(7) Identify X and Y in the following sequence
[A] X = KCN, Y = LiAlH4
[B] X = KCN, Y = H3O+
[C] X = CH3Cl, Y = AlCl3 HCl
[D] X = CH3NH2, Y = HNO2
Answer: X = KCN, Y = LiAlH4
(8) In the following sequence of reactions:
[A] n-propylamine
[B] isopropylamine
[C] ethylamine
[D] ethylmethylamine
Answer: ethylmethylamine
(9)
[A]
[B]
[C]
[D]
Answer:
(10) Identifay Z in the series
[A] C2H5I
[B] C2H5OH
[C] CHI3
[D] CH3CHO
Answer: CHI3
(11) Of the options give, the one statement about trichloromethane (Chloroform) that is correct is ____
[A] It should be stored in a well ventilated place, exposed to sunlight.
[B] In the presence of air or light, chloroform is slowly oxidized into a poisonous compound phosgene.
[C] Chloroform gets reduced with zinc dust and water to form Methylene chloride.
[D] Chloroform is converted into carbon tetrachloride on warming with silver powder.
Answer: Chloroform is converted into carbon tetrachloride on warming with silver powder.
(12) Aryl chlorides and bromides can be easily prepared by ____ of arenes with chlorine and bromine respectively in the presence of Lewis acid catalysts like iron or iron (III) chloride.
[A] Electrophilic addition
[B] Electrophilic substitution
[C] Nucleophilic addition
[D] Nucleophilic substitution
Answer: Electrophilic substitution
(13) At room temperature ethyl chloride, methyl bromide, ethyl chloride and some chlorofluoromethanes exist as____.
[A] Liquid
[B] Solid
[C] Gas
[D] Some of them solid and other liquid
Answer: Gas
(14) When we go down the group 17 in the periodic table, the one option that is incorrect is ____.
[A] size of the halogen atoms increases
[B] change in size of halogen atom results in increase in carbon-halogen bond length
[C] change in size of halogen atom results in carbon-halogen bond enthalpy (kJ mol-1) decrease
[D] reactivity of halogens increases
Answer: reactivity of halogens increases
(15) Triodomethane (Iodoform) was earlier used as an
[A] analgesic
[B] antiseptic
[C] antihistamine
[D] antibiotic
Answer: antiseptic
(16) The chloroflurocarbon compounds of methane and ethane are collectively known as ____
[A] haloalkanes
[B] alkyl halides
[C] Freons
[D] DDT
Answer: Freons
(17) Haloalkanes react with KCN to form__________ as main product, but with AgCN, it form _______ as the chief product.
[A] alkyl cyanides; isocyanides
[B] isocyanides; alkyl cyanides
[C] isocyanides; isocyanides
[D] alkyl cyanides; alkyl cyanides
Answer: alkyl cyanides; isocyanides
(18) In Fittig reaction, aryl halides when treated with ____ in dry ether give an analogous compound in which two aryl groups are joined together.
[A] Potassium
[B] Magnesium
[C] Sodium
[D] Calcium
Answer: Sodium
(19) Of the following, ____________ is not a monohalo-organic compound.
[A] CH2=CHCl
[B] CH2=CHCH2Br
[C] CH2Cl2
[D] CH3CH2CH2F
Answer: CH2Cl2
(20) The metal present in Grignard reagents is___.
[A] Sodium
[B] Potassium
[C] Magnesium
[D] Calcium
Answer: Magnesium

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