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Organic Chemistry Questions and Answers – Alkyl Halides | Organic Chemistry Multiple Choice Questions and Answers

(1) Which C-X bond has the highest bond energy per mole?
[A] C-Br
[B] C-Cl
[C] C-F
[D] C-I
Answer: C-F
(2) Which alkyl halide has the highest reactivity for a particular alkyl group?
[A] R-F
[B] R-Cl
[C] R-I
[D] R-Br
Answer: R-I

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(3) When ethyl chloride reacts with nascent hydrogen, what is the formed product?
[A] Methane
[B] Propane
[C] Butane
[D] Ethane
Answer: Ethane
(4) Which alkyl halide out of the following may follow both SN1 and SN2 mechanism?
[A] CH3-X
[B] (CH3)2CH-X
[C] (CH3)3C-X
[D] (CH3)3C-CH2-X
Answer: (CH3)2CH-X
(5) When two moles of ethyl chloride react with two moles of sodium in the presence of ether what will be formed?
[A] 2 moles of ethane
[B] 1 moles of ethane
[C] 2 moles of butane
[D] 1 moles of butane
Answer: 1 moles of butane
(6) Which of the following halide can give best SN2 reaction?
[A] Primary alkyl halide
[B] Tertiary alkyl halide
[C] Secondary alkyl halide
[D] All can give SN2 reaction at same rate
Answer: Primary alkyl halide
(7) Why alkyl halides are considered to be very reactive compounds towards nucleophile?
[A] they have an electrophilic carbon & a bad leaving group
[B] they have a nucleophilic carbon & a good leaving group
[C] they have an electrophilic carbon
[D] they have an electrophilic carbon & a good leaving group
Answer: they have an electrophilic carbon & a good leaving group
(8) In primary alkyl halides, carbon attached to the halogen atom is further attached to how many carbon atoms?
[A] 1
[B] 2
[C] 3
[D] 4
Answer: 1
(9) Which of the following is not the method of preparation of alkyl halide?
[A] Darzen’s method
[B] Halogenation of alkene
[C] Addition of HX on alkenes
[D] Hydration of alkene
Answer: Hydration of alkene
(10) Which of the following reactant gives the best method of preparation of alkyl halides when reacts with alcohol?
[A] Zn/HCl
[B] PCl5
[C] SOCl2/ Pyridine
[D] PCl3
Answer: SOCl2/ Pyridine

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