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Organic Chemistry Questions and Answers – Preparation of Aldehydes | Organic Chemistry Multiple Choice Questions and Answers

(1) Primary alcohol is gently heated to produce aldehyde in presence of acidified solution of which of the following compound?
[A] hydroxide
[B] dichromate
[C] ethanol
[D] ethanal
Answer: dichromate
(2) In the given reaction, what will be the product P?

[A] RCH2OH
[B] RCOOH
[C] RCHO
[D] RCH3
Answer: RCHO

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(3) What is the name of the given reaction of preparation of aldehyde?

[A] Reimer-Tiemann reaction
[B] Cannizzaro reaction
[C] Rosenmund reaction
[D] Reformatsky reaction
Answer: Rosenmund reaction
(4) Which Catalyst is used in Rosenmund reduction?
[A] Pd / BaSO4
[B] Zn-Hg couple
[C] LiAlH4
[D] Ni/H2
Answer: Pd / BaSO4
(5) On heating calcium acetate and calcium formate, the product formed is which of the following?
[A] CH3COCH3
[B] CH3CHO
[C] HCHO+CaCO3
[D] CH3CHO+CaCO3
Answer: CH3CHO+CaCO3
(6) In the Rosenmund’s reduction, BaSO4 taken with catalyst Pd acts as which of the following?
[A] Promotor
[B] Catalytic poison
[C] Cooperator
[D] Absorber
Answer: Catalytic poison
(7) Catalyst SnCl2/HCl is used in which of the following method of synthesis of aldehyde?
[A] Stephen’s reduction
[B] Cannizzaro reaction
[C] Clemmensen’s reduction
[D] Rosenmund’s reduction
Answer: Stephen’s reduction
(8) What is the product X in the following reaction?

[A] C6H5CH3
[B] C6H5CH2Cl
[C] C6H5CHO
[D] C6H5COOH
Answer: C6H5CHO
(9) Which of the following gases when passed through warm dilute solution of H2SO4 in presence of HgSO4 gives acetaldehyde?
[A] CH4
[B] C2H6
[C] C2H4
[D] C2H2
Answer: C2H2
(10) O3 reacts with CH2=CH2 to form ozonide. On hydrolysis it forms which of the following?
[A] Ethylene oxide
[B] HCHO
[C] Ethylene glycol
[D] Ethyl alcohol
Answer: HCHO

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