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UV-Visible Multiple Choice Spectroscopy Questions and Answers | UV-Visible MCQs

(1) Select the wavelength range corresponding to UV-visible region.
[A] 400-800 nm
[B] 200-800 nm
[C] 25 μm-2.5 μm
[D] 2.5 μm – 1mm
Answer: 200-800 nm
(2) If the above compound was completely reduced, what will be the possible transitions it can undergo?
[A] n→p*
[B] s→s*
[C] p→p*
[D] n→s*, s→s*
Answer: n→s*, s→s*

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(3) On increasing pH, phenol shows
[A] Q,R
[B] P,R
[C] Q,S
[D] P,S
Answer: P,S
(4) The approximate lambda max for the above compound will be
[A] 214 nm
[B] 217 nm
[C] 222 nm
[D] 227 nm
Answer: 222 nm
(5) The possible transitions for water molecule in UV-visible region are
[A] σ →σ *
[B] n→π *, π→π *
[C] σ→σ *, n→π *
[D] n → σ*
Answer: n → σ*
(6) Choose the right statement
[A] Homoannular diene is called as transoid
[B] Cisoid shows less intense absorption
[C] The base value of transoid is 214 nm
[D] Exocyclic double bond causes a bathochromic shift of 30 nm
Answer: The base value of transoid is 214 nm
(7) The increment for α alkyl substitution on enones is
[A] 18
[B] 12
[C] 10
[D] 5
Answer: 10
(8) The λmax in α,β-unsaturated acids can be determined by
[A] Wood ward fieser
[B] Nielsen rules
[C] Fieser-kuhn rules
[D] All of the above
Answer: Wood ward fieser
(9) The number of double bonds present in carotene is
[A] 5
[B] 10
[C] 11
[D] 18
Answer: 11
(10) Select one of the statements that is CORRECT regarding enones.
[A] n→π * is forbidden
[B] π →π * is forbidden
[C] Both n→π * and π →π * are forbidden
[D] n→π * is forbidden but π →π * is allowed
Answer: n→π * is forbidden

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