CBSE Class 12 Chemistry Quiz | CBSE Class 12 Chemistry Objective Type Questions & Answers

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Questions
21 An unripe mango placed in a concentrated salt solution to prepare pickle, shrivels because _________ .
A it gains water due to osmosis.
B it loses water due to reverse osmosis.
C it gains water due to reverse osmosis.
D it loses water due to osmosis.

Answer: it loses water due to reverse osmosis.
22 In comparison to a 0.01 M solution of glucose, the depression in freezing point of a 0.01 M MgCl2 solution is _________ .
A the same
B about twice
C about three times
D about six times

Answer: about three times
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23 Which of the following aqueous solutions should have the highest boiling point?
A 1.0 M NaOH
B 1.0 M Na2SO4
C 1.0 M NH4NO3
D 1.0 M KNO3

Answer: 1.0 M Na2SO4
24 Considering the formation, breaking and strength of hydrogen bond, predict which of the following mixtures will show a positive deviation from Raoult’s law?
A Methanol and acetone.
B Phenol and aniline.
C Chloroform and acetone.
D Nitric acid and water.

Answer: Methanol and acetone.
25 Low concentration of oxygen in the blood and tissues of people living at high altitude is due to _________ .
A low temperature
B low atmospheric pressure
C high atmospheric pressure
D both low temperature and high atmospheric pressure

Answer: low atmospheric pressure
26 The number of moles of NaCl in 3 litres of 3M solution is
A 9
B 27
C 1
D 3

Answer: 9
27 The molality of pure water is
A 60.5
B 55.5
C 50.5
D 18

Answer: 55.5
28 If E°Fe2+/Fe = -0.441 V and E°Fe2+/Fe2+ = 0.771 V, the standard EMF of the reaction, Fe + 2Fe3+ → 3Fe2+ will be
A 1.212 V
B 1.653 V
C 0.111 V
D 0.330 V

Answer: 1.212 V
29 The reaction, 3ClO– (aq) → ClO3 (aq) + 2Cl– (aq) is an example of
A Oxidation reaction
B Reduction reaction
C Disproportionation reaction
D Decomposition reaction

Answer: Disproportionation reaction
30 NH4NC>3 is used in salt bridge because
A it forms a jelly like material with agar-agar.
B it is a weak electrolyte.
C it is a good conductor of electricity.
D the transport number of NH4+ and NO3– ions are almost equal.

Answer: the transport number of NH4+ and NO3– ions are almost equal.
31 limiting molar conductivity of Ca2+ and Cl– are 119.0 and 76.3 S cm2 mol-1, then the value of limiting molar conductivity of CaCl2 will be
A 195.3 S cm2 mol-1
B 271.6 S cm2 mol-1
C 43.3 S cm2 mol-1
D 314.3 S cm2 mol-1.

Answer: 271.6 S cm2 mol-1
32 The charge required for the reduction of 1 mol of MnO2– to MnO2 is
A 1 F
B 3 F
C 6 F
D 5 F

Answer: 3 F
33 Λ of M/32 solution of weak acid is 8 S cm2 mol-1 and limiting molar conductivity is 400 S cm2 mol1. Ka for acid is
A 1.25 × 10-6
B 6.25× 10-4
C 1.25 × 10-4
D 1.25 × 10-5

Answer: 1.25 × 10-5
34 While charging the lead storage battery _________ .
A PbSO4 anode is reduced to Pb.
B PbSO4 cathode is reduced to Pb.
C PbSO4 cathode is oxidised to Pb.
D PbSO4 anode is oxidised to PbO2.

Answer: PbSO4 anode is reduced to Pb.
35 A conductivity cell containing electrodes made up of
A Gold
B Silver
C Platinised platinum
D Copper

Answer: Platinised platinum
36 Ag+(aq) + e– → Ag(s) E° = + 0.80 V Fe2+(aq)+ + 2e– → Fe(s) E° = – 0.44 V What is emf of Fe(s) + 2Ag+(aq) → Fe2+(aq) + 2Ag(s)
A 1.16 V
B 1.24 V
C 2.04 V
D -1.16 V

Answer: 1.24 V
37 A new galvanic cell of E^u more than E°dl of Daniel cell is connected to Daniel cell in a manner that new cell gives electrons to cathode, what will happen
A Ecell will increase
B Ecell will decrease
C No change will take place
D Daniel cell will work as electrolytic cell where Zn will be deposite on zinc rod and copper will dissolve from copper rod.

Answer: Ecell will decrease
38 The emf of the cell: Ni / Ni2+ (1.0 M) // Au3+ (1.0 M) / Au (E° = -0.25 V for Ni2+/Ni; E° = 1.5 V for Au3+/Au) is
A 1.25 V
B -1.25 V
C 1.75 V
D 2.0 V

Answer: 1.75 V
39 The half life period of first order reaction is 1386 seconds. The specific rate constant of the reaction is
A 0.5 × 10-3 s-1
B 5.0 × 10-3 s-1
C 0.5 × 10-2 s-1
D 5.0 × 10-2 s-1

Answer: 0.5 × 10-3 s-1
40 The rate constant of a reaction A → B is 0.6 × 103 mole per second. If the concentration of [A] is 5 M, then what will be concentration of [B] after 20 months?
A 3.60 M
B 0.36 M
C 0.72 M
D None of these

Answer: 0.72 M

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