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Organic Chemistry Questions and Answers – Chemical Properties of Aldehydes | Organic Chemistry Multiple Choice Questions and Answers

(1) During a reaction of Tollens test, the formation of mirror inside the tube is due to which of the following?
[A] silver ions
[B] silver atoms
[C] silver compounds
[D] silver nitrate
Answer: silver atoms
(2) Reduction of Aldehydes to hydrocarbon take place in the presence of which of the following?
[A] Zn amalgam and HCl acid
[B] Pd/BaSO4
[C] Anhydrous AlCl3
[D] Ni/Pt
Answer: Zn amalgam and HCl acid

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(3) For C6H5CHO which of the following is incorrect?
[A] On oxidation it yields benzoic acid
[B] It is used in perfumery
[C] It is an aromatic aldehyde
[D] On reduction yields phenol
Answer: On reduction yields phenol
(4) Which of the following compound will undergo self-aldol condensation in the presence of cold dilute alkali?
[A] C6H5CHO
[B] CH3CH2CHO
[C] CH≡C−CHO
[D] CH2=CH−CHO
Answer: CH3CH2CHO
(5) Which of the following will not undergo aldol condensation?
[A] Acetaldehyde
[B] Propanaldehyde
[C] Benzaldehyde
[D] Trideuteroacetaldehyde
Answer: Benzaldehyde
(6) Acetaldehyde cannot show which of the following test?
[A] Iodoform test
[B] Lucas test
[C] Benedict’s test
[D] Tollen’s test
Answer: Lucas test
(7) What will be the product if aldehyde reacts with NaOH?
[A] Benzyl alcohol
[B] Benzoic alcohol
[C] Hydrobenzamide
[D] Cinnamic acid
Answer: Benzyl alcohol
(8) To distinguish between formaldehyde and acetaldehyde, we require which of the following reagent?
[A] Tollen’s reagent
[B] Fehling’s solution
[C] Schiff’s reagent
[D] Caustic soda solution
Answer: Caustic soda solution
(9) If formaldehyde and KOH are heated, then we get which of the following compound?
[A] Acetylene
[B] Methane
[C] Methyl alcohol
[D] Ethyl formate
Answer: Methyl alcohol
(10) Acetaldehyde reacts with C2MH5MgCl the final product is which of the following?
[A] An aldehyde
[B] A ketone
[C] A primary alcohol
[D] A secondary alcohol
Answer: A secondary alcohol

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