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Organic Chemistry Questions and Answers – Physical Properties of Amines | Organic Chemistry Multiple Choice Questions and Answers

(1) Which of the following compound is expected to be most basic?
[A] Aniline
[B] Methylamine
[C] Hydroxylamine
[D] Ethylamine
Answer: Ethylamine
(2) A solution of methyl amine shows which type of property with litmus paper?
[A] Turns blue litmus red
[B] Turns red litmus blue
[C] Does not affect red or blue litmus
[D] Bleaches litmus
Answer: Turns red litmus blue

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(3) Which of the following statement is true about methyl amine?
[A] Methyl amine is slightly acidic
[B] Methyl amine is less basic than NH3
[C] Methyl amine is stronger base than NH3
[D] Methyl amine forms salts with alkali
Answer: Methyl amine is stronger base than NH3
(4) By the presence of a halogen atom in the ring, what is the effect of this on basic properties of aniline?
[A] Increased
[B] Decreased
[C] Unchanged
[D] Doubled
Answer: Increased
(5) What is the characteristic smell of liquid amines?
[A] Fish like smell
[B] Rotten egg smell
[C] Fruity smell
[D] Bitter almond smell
Answer: Fish like smell
(6) Which of the following have less melting point than amine?
[A] Alcohol
[B] Phosphine
[C] Carboxylic acid
[D] Ether
Answer: Phosphine
(7) Which of the following amine has highest boiling point?
[A] Butyl amine
[B] Diethylamine
[C] Triethylamine
[D] Dipropylamine
Answer: Dipropylamine
(8) What is the correct decreasing order of the basic character of the three amines and ammonia?
[A] NH3 > CH3NH2 > C2H5NH2 > C6H5NH2
[B] C2H5NH2 > CH3NH2 > NH3 > C6H5NH2
[C] C6H5NH2 > C2H5NH2 > CH3NH2 > NH3
[D] CH3NH2 > C2H5NH2 > C6H5NH2 > NH3
Answer: C2H5NH2 > CH3NH2 > NH3 > C6H5NH2
(9) Unpleasant smelling carbylamines are formed by heating alkali and chloroform with which of the following?
[A] Any amine
[B] Any aliphatic amine
[C] Any aromatic amine
[D] Any primary amine
Answer: Any primary amine
(10) Which statement is an incorrect statement?
[A] Amines form hydrogen bond
[B] Ethyl amine has higher boiling point than propane
[C] Methyl amine is more basic than ammonia
[D] Dimethyl amine is less basic than methyl amine
Answer: Dimethyl amine is less basic than methyl amine

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