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Organic Chemistry Questions and Answers – Chemical Properties of Amines – 2 | Organic Chemistry Multiple Choice Questions and Answers

(1) A primary amine can be converted to an alcohol by the action of which of the following?
[A] Alkali
[B] Nitrous acid
[C] Reducing agent
[D] Oxidizing agent
Answer: Nitrous acid
(2) The amine which can react with C6H5−SO2−Cl to form a product insoluble in alkali shall be, is which of the following?
[A] Primary amine
[B] Secondary amine
[C] Tertiary amine
[D] Both primary and secondary amines
Answer: Secondary amine

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(3) A mixture of benzene and aniline can be separated by which of the following?
[A] Hot water
[B] dil. HCl
[C] dil. NaOH
[D] Alcohol
Answer: dil. HCl
(4) An organic amino compound reacts with aqueous nitrous acid at low temperature to produce an oily nitroso amine. What is this compound?
[A] CH3NH2
[B] CH3CH2NH2
[C] CH3CH2NH.CH2CH3
[D] (CH3CH2)3
Answer: CH3CH2NH2
(5) Reaction of aniline with benzaldehyde is which type of reaction?
[A] Polymerisation
[B] Condensation
[C] Addition
[D] Substitution
Answer: Condensation
(6) In the reaction, what is the compound C6H5N=CHC6H5 is known as?

C6H5CHO + C6H5NH2 → C6H5N=HCC6H5 + H2O

[A] Aldol
[B] Schiffs reagent
[C] Schiffs base
[D] Benedict reagent
Answer: Schiffs base
(7) Electrophilic substitution of aniline with bromine in presence of gacial acetic acid gives which of the following?
[A] 1, 4, 6-tribromo aniline
[B] 2, 4, 6-tribromo aniline
[C] 4-bromo aniline
[D] 3-bromo aniline
Answer: 4-bromo aniline
(8) During acetylation of amines what is replaced by acetyl groups?
[A] Hydrogen atom attached to nitrogen atom
[B] One or more hydrogen atoms attached to carbon atom
[C] One or more hydrogen atoms attached to nitrogen atom
[D] Hydrogen atoms attached to either carbon atom or nitrogen atom
Answer: One or more hydrogen atoms attached to nitrogen atom
(9) Ethyl amine on acetylation gives which of the following?
[A] N-ethyl acetamide
[B] Acetamide
[C] Methyl acetamide
[D] Propyl acetamide
Answer: N-ethyl acetamide
(10) p-chloro aniline and anilinium hydrogen chloride can be distinguished by which of the following?
[A] Sandmaeyer reaction
[B] Carbyl amine reaction
[C] Hinsberg’s reaction
[D] AgNO3
Answer: AgNO3

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