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Class 12 Chemistry Chapter 7 p Block Elements MCQs | Class 12 Chemistry Chapter 7 p Block Elements Multiple Choice Questions (MCQs) and Answers

(1) In the presence of KF, AlF3 is soluble in HF. Find the complex formed

[A] K3[AlF6]
[B] AlH3
[C] K[AlF3H]
[D] K3[AlF3H3]
Answer: K3[AlF6]
(2) S-S bond is present in which of the ion pairs

[A] S2O72-, S2O32-
[B] S4O62-, S2O72-
[C] S2O72-, S2O82-
[D] S4O62-, S2O32-
Answer: S4O62-, S2O32-
(3) Which is the correct order of decreasing bond dissociation enthalpy?

[A] F2 > Cl2 > Br2 > I2
[B] I2 > Br2 > Cl2 > F2
[C] Cl2 > Br2 > F2 > I2
[D] Br2 > I2 > F2 > Cl2
Answer: Br2 > I2 > F2 > Cl2
(4) Oxygen is not released on heating which of the compounds?

[A] (NH4)2Cr2O7
[B] K2Cr2O7
[C] Zn(ClO3)2
[D] KClO3
Answer: (NH4)2Cr2O7
(5) Which of the species has a permanent dipole moment?

[A] SF4
[B] SiF4
[C] BF3
[D] XeF4
Answer: SF4
(6) Which of the statement is incorrect for XeO4 ?
[A] four pπœ‹-dπœ‹ bonds are present
[B] four sp3 – p 𝜎 bonds are present
[C] It has a tetrahedral shape
[D] It has a square planar shape
Answer: It has a square planar shape
(7) P4O10 has ______ bridging O atoms
[A] 4
[B] 5
[C] 6
[D] 2
Answer: 6
(8) Find the amphoteric oxide

[A] CaO2
[B] CO2
[C] SnO2
[D] SiO2
Answer: SnO2
(9) Graphite has a structural similarity with

[A] B2H6
[B] B4C
[C] B
[D] BN
Answer: BN
(10) Which is the correct order of decreasing acidity of lewis acids?

[A] BBr3 > BCl3 > BF3
[B] BF3 > BCl3 > BBr3
[C] BCl3 > BF3 > BBr3
[D] BBr3 > BF3 > BCl3
Answer: BBr3 > BCl3 > BF3
(11) Boron form covalent Compound due to
[A] Higher ionisation enthalpy
[B] Lower ionisation enthalpy
[C] Small size
[D] Both (a) and (c)
Answer: Both (a) and (c)
(12) In diborane the Two H-B-H angles are nearly
[A] 60° , 120°
[B] 95° ,120° 
[C] 95° ,150° 
[D] 120° ,180°
Answer: 95° ,120° 
(13) The stability of +1 oxidation state increases in the sequence
[A] Al< Ga< In< Tl
[B] Tl< In< Ga< Al
[C] In< Tl< Ga< Al
[D] Ga< In< Al< Tl
Answer: Al< Ga< In< Tl
(14) Which of the following is most acidic
[A] Na2O
[B] Mgo
[C] Al2O3
[D] Cao
Answer: Al2O3
(15) Cohen Orthoboric acid (H3BO3) is strongly heated, the residue is
[A] Meta boric acid
[B] Boron
[C] Al2O3, 2H2O
[D] None of above
Answer: Meta boric acid
(16) Bauxite has the composition
[A] Al2O3
[B] Al2O3, H2O
[C] Al2O3 • 2H2O
[D] All the given
Answer: Al2O3 • 2H2O
(17) Which one of the following is correct statement
[A] The hydroxide of aluminium is more acidic than that of boron
[B] The hydroxide of boron is basic, while that of aluminium is amphoteric
[C] The hydroxide of boron is acidic, while that of aluminium is amphoteric
[D] The hydroxide of boron & aluminium are amphoteric
Answer: The hydroxide of boron is acidic, while that of aluminium is amphoteric
(18) AlCl3 is
[A] Anhydrous & covalent
[B] Anhydrous & ionic
[C] Covalent & basic
[D] Coordinate & acidic
Answer: Anhydrous & covalent
(19) Aluminium (III) chloride forms a dimer because
[A] Higher coordination number can be achieved by aluminium
[B] Aluminium has high ionization energy
[C] Aluminium belongs to III group
[D] It cannot form a trimer
Answer: Higher coordination number can be achieved by aluminium
(20) Aluminium has a great affinity for oxygen & it’s oxidation is an exothermic process. This fact is used in
[A] Preparing thin foils of aluminium
[B] Making utensils
[C] Preparing duralumin alloy
[D] Thermite welding
Answer: Thermite welding

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