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Organic Chemistry Multiple Choice Questions and Answers – Redox Reactions

(1) KMnO4 reacts with oxalic acid according to the equation given below. Here 20 mL of 0.1 M KMnO4 is equivalent to how many mL and molarity of H2C2O4?

[A] 20 mL of 0.5 M H2C2O4
[B] 50 mL of 0.5 M H2C2O4
[C] 50 mL of 0.1 M H2C2O4
[D] 20 mL of 0.1 M H2C2O4
Answer: 50 mL of 0.1 M H2C2O4
(2) Excess of KI reacts with CuSO4 solution and then Na2S2O3 solution is added to it. Which of the statement is incorrect for this reaction?
[A] Na2S2O3 is oxidized
[B] CuI2 is formed
[C] Cu2I2 is formed
[D] Evolved I2 is reduced
Answer: CuI2 is formed

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(3) How many number of moles of KMnO4 will react with 180 gm H2C2O4 according to given reaction?

KMnO4 + H2C2O4 → 2C02 + Mn2+

[A] 4/5
[B] 2/5
[C] 1/5
[D] 4/3
Answer: 4/5
(4) What is the mass of K2Cr2O7 required to produce 254 gm I2 from KI solution? Given: K2Cr2O7 + 2KI → 2Cr3+ + I2
[A] 49 g
[B] 98 g
[C] 9.8 g
[D] 4.9 g
Answer: 98 g
(5)  What is the volume of 0.05 M KMnO4 which will react with 50 ml of 0.1 M H2S in acidic medium (H2S → S02)?
[A] 60 ml
[B] 6 ml
[C] 12 ml
[D] 120 ml
Answer: 120 ml
(6) What is the mass of Fe304 if it reacts completely with 25 ml of 0.3m K2Cr2O7?
[A] 1 .44 g
[B] 10.44 g
[C] 104.4 g
[D] 14.4 g
Answer: 10.44 g
(7) What is the concentration of H2O2 solution of 20 ml of H2O2 solution which will react completely with 10 ml of 2 M KMnO4 in acidic medium?
[A] 1.25 M
[B] 5 M
[C] 2.5 M
[D] 25 M
Answer: 2.5 M
(8) How many moles of KCI are required to produce 10 mol Cl2 by the reaction with KCIO3?
[A] 1.66 mole
[B] 13.33 mole
[C] 0.66 mole
[D] 16.66 mole
Answer: 16.66 mole
(9)

How many moles of KMnO4 are required for complete oxidation of 1.25 mol Cu2S?

Cu2S → Cu+2 + SO2

[A] 1 mole
[B] 3 moles
[C] 2 moles
[D] 5 moles
Answer: 2 moles
(10) What is the volume strength of H2O2 of its 11.2 ml requires 30 ml of 0.5 M 2Cr2O7?
[A] 35
[B] 55
[C] 25
[D] 45
Answer: 45

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