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Organic Chemistry Multiple Choice Questions and Answers – Reaction Mechanism of Organic Compounds

(1) Why are aryl halides less reactive towards nucleophilic substitution reactions as compared to alkyl halides?
[A] The formation of a less stable carbanion
[B] Longer carbon halogen bond
[C] The inductive effect
[D] Sp2-hybridized carbon attached to the halogen
Answer: Sp2-hybridized carbon attached to the halogen
(2) What will be the (X) in the below mentioned reaction sequence?

[A]
[B]
[C]
[D]
Answer: (a)

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(3) In the following reaction sequence, what will be X?

[A] Benzoic acid
[B] Salicylic acid
[C] Phenol
[D] Aniline
Answer: Aniline
(4) Which of the following is not true for SN1 reactions?
[A] They occur through a single step concerted reaction
[B] They are favoured by polar solvents
[C] Tertiary alkyl halides generally react through this mechanism
[D] Concentration of nucleophile does not affect the rate of such reactions
Answer: They occur through a single step concerted reaction
(5) What is not true about below reaction?

[A] Major product is given by SN1 reaction
[B] Through E1 mechanism 3 alkenes are formed
[C] 3-Methylpentane-3-ol is also formed as one of the product
[D] Fractional distillation of elimination product will give two fractions
Answer: Fractional distillation of elimination product will give two fractions
(6) What will be the total number of isomers formed when 2-methyl butane is subjected to monochlorination?
[A] 5
[B] 4
[C] 3
[D] 6
Answer: 6
(7) The number of substitution products formed when metabromo anisole is treated with KNH2/NH3?
[A] 1
[B] 2
[C] 3
[D] 4
Answer: 3
(8) How many number of pie e- is present in benzene?
[A] 6
[B] 7
[C] 8
[D] 9
Answer: 7
(9) What will be the final product in the below reaction?

[A] (a)
[B] (b)
[C] (c)
[D] (d)
Answer: (a)
(10) Which of the following structures represent the correct major product for the below reaction?

[A] (a)
[B] (b)
[C] (c)
[D] (d)
Answer: (c)

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