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Organic Chemistry Multiple Choice Questions and Answers – Resonance and Aromaticity

(1) Resonance forms are in equilibrium with each other.
[A] True
[B] False
Answer: False
(2) Identify the false statement regarding resonance.
[A] As the number of charges increases, the resonance forms gets more significant
[B] Zero charge of resonance is the most significant one
[C] Atoms with full octet resonance form are more stable when compared with the one with unfilled octet
[D] Resonance is unstable in case of unfilled octet of nitrogen atom
Answer: As the number of charges increases, the resonance forms gets more significant

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(3) Identify the correct sequence according to electronegativity.
[A] F > NH2 > CH3 >OH`
[B] NH2 `> F` >CH3` > OH`
[C] NH2 `> OH` > CH3` > F`
[D] F` > OH` > NH2` > CH3`
Answer: F` > OH` > NH2` > CH3`
(4) Identify the correct sequence with respect to Inductive effects.
[A] CF3`> CH2F`> CHF2`> CF3`
[B] CF3`> CHF2`> CH2F`> CH3`
[C] CH3`> CH2F`> CHF2`> CF3`
[D] CH3`> CHF2`> CH2F`v CF3`
Answer: CF3`> CHF2`> CH2F`> CH3`
(5) Stability sequence: primary carbocation > secondary carbocation > tertiary carbocation. Is this sequence correct?
[A] Yes
[B] No
Answer: No
(6) Identify the incorrect statement regarding aromaticity.
[A] It is the extra stability possessed by a molecule
[B] p-orbitals must be planar and overlap
[C] Cyclic delocalization takes place
[D] It does not follow Huckel’s rule
Answer: It does not follow Huckel’s rule
(7) Aromatic rings do not have resonance structures.
[A] False
[B] True
Answer: False
(8) Select the correct statement regarding the aromatic nitrogen molecule.
[A] It is not hybridized
[B] It is sp hybridized
[C] It is sp2 hybridized
[D] It is sp3 hybridized
Answer: It is sp2 hybridized
(9) Can a linear molecule have aromaticity.
[A] Yes
[B] No
Answer: No
(10) Select the incorrect statement.
[A] A resonance may sometimes cause sp3 atoms to become sp2 hybridized
[B] Delocalizing one lone pair causes aromaticity
[C] One lone pair will be counted as two pi electrons according to Huckel’s equation
[D] Two sigma bonds make up a double bond
Answer: Two sigma bonds make up a double bond

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